Publications D4

2318 Phylogenomic Analysis of the Microviridin Biosynthetic Pathway Coupled with Targeted Chemo-Enzymatic Synthesis Yields Potent Protease Inhibitors M. N. Ahmed, E. Reyna-González, B. Schmid, V. Wiebach, R. D. Süssmuth, E. Dittmann, D. P. Fewer ACS Chemical Biology 2017, 12, 1538–1546, 10.1021/acschembio.7b00124

2277 Peptidyl-Prolyl Model Study: How Does the Electronic Effect Influence the Amide Bond Conformation? P. K. Mykhailiuk, V. Kubyshkin, T. Bach, N. Budisa The Journal of Organic Chemistry 2017, 82, 8831–8841, 10.1021/acs.joc.7b00803

2276 The Regioselective Synthesis of o-Nitrobenzyl DOPA Derivatives T. Schneider, J. Martin, P. Durkin, V. Kubyshkin, N. Budisa Synthesis 2017, 49, 2691–2699, 10.1055/s-0036-1588766

2275 Hydrolysis, polarity, and conformational impact of C-terminal partially fluorinated ethyl esters in peptide models V. Kubyshkin, N. Budisa Beilstein Journal of Organic Chemistry 2017, 13, 2442–2457, 10.3762/bjoc.13.241

2274 Amide rotation trajectories probed by symmetry V. Kubyshkin, N. Budisa Organic & Biomolecular Chemistry 2017, 15, 6764–6772, 10.1039/C7OB01421J

2273 Selective¹⁹F-Labeling of Functionalized Carboxylic Acids with Difluoromethyl Diazomethane (CF₂HCHN₂) P. K. Mykhailiuk, I. Kishko, V. Kubyshkin, N. Budisa, J. Cossy Chemistry - A European Journal 2017, 23, 13279–13283, 10.1002/chem.201703446

2270 Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminum Chlorofluoride B. Calvo, T. Braun, E. Kemnitz ChemCatChem 2018, 10, 403–406, 10.1002/cctc.201701327

2269 Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C−F Activation Steps at a Lewis Acidic Aluminum Fluoride G. Meißner, K. Kretschmar, T. Braun, E. Kemnitz Angewandte Chemie 2017, 129, 16556–16559, 10.1002/ange.201707759

2268 Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex R. Laubenstein, M. Ahrens, T. Braun Zeitschrift für anorganische und allgemeine Chemie 2017, 643, 1723–1729, 10.1002/zaac.201700276

2267 Synthesis and reactivity of a cationic palladium complex as possible intermediate in a Suzuki-Miyaura cross-coupling reaction J. Kohlmann, T. Braun Journal of Fluorine Chemistry 2017, 203, 140–145, 10.1016/j.jfluchem.2017.08.003

2266 Et₃GeH versus Et₃SiH: controlling reaction pathways in catalytic C–F bond activations at a nanoscopic aluminum chlorofluoride G. Meißner, D. Dirican, C. Jäger, T. Braun, E. Kemnitz Catalysis Science & Technology 2017, 7, 3348–3354, 10.1039/c7cy00845g

2232 Iron Exsolution Phenomena in Lanthanum Strontium Ferrite SOFC Anodes T. Götsch, C. Praty, M. Grünbacher, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, M. Tada, H. Matsui, N. Ishiguro, B. Kloetzer, S. Penner ECS Transactions 2017, 78, 1327–1341, 10.1149/07801.1327ecst

2231 Surface chemistry and stability of metastable corundum-type In₂O₃ E. M. Köck, M. Kogler, C. Zhuo, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, S. Penner Physical Chemistry Chemical Physics 2017, 19, 19407–19419, 10.1039/c7cp03632a

2230 Surface chemistry of pure tetragonal ZrO₂and gas-phase dependence of the tetragonal-to-monoclinic ZrO₂transformation E. M. Köck, M. Kogler, T. Götsch, L. Schlicker, M. F. Bekheet, A. Doran, A. Gurlo, B. Klötzer, B. Petermüller, D. Schildhammer, N. Yigit, S. Penner Dalton Transactions 2017, 46, 4554–4570, 10.1039/c6dt04847a

2170 Reversible light-dependent molecular switches on Ag/AgCl nanostructures W. Song, C. J. Querebillo, R. Götz, S. Katz, U. Kuhlmann, U. Gernert, I. M. Weidinger, P. Hildebrandt Nanoscale 2017, 9, 8380–8387, 10.1039/C7NR02760E

2169 An expanded genetic code for probing the role of electrostatics in enzyme catalysis by vibrational Stark spectroscopy J. S. Völler, H. Biava, P. Hildebrandt, N. Budisa Biochimica et Biophysica Acta (BBA) - General Subjects 2017, 1861, 3053–3059, 10.1016/j.bbagen.2017.02.009

2168 Characterization of anisotropically shaped silver nanoparticle arrays via spectroscopic ellipsometry supported by numerical optical modeling D. Gkogkou, T. Shaykhutdinov, T. W. H. Oates, U. Gernert, B. Schreiber, S. Facsko, P. Hildebrandt, I. M. Weidinger, N. Esser, K. Hinrichs Applied Surface Science 2017, 421, 460–464, 10.1016/j.apsusc.2016.10.105

2163 Determination of the Local Electric Field at Au/SAM Interfaces Using the Vibrational Stark Effect J. K. Staffa, L. Lorenz, M. Stolarski, D. H. Murgida, I. Zebger, T. Utesch, J. Kozuch, P. Hildebrandt The Journal of Physical Chemistry C 2017, 121, 22274–22285, 10.1021/acs.jpcc.7b08434

2117 Activation of CS₂and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes T. Ahrens, B. Schmiedecke, T. Braun, R. Herrmann, R. Laubenstein European Journal of Inorganic Chemistry 2017, 2017, 713–722, 10.1002/ejic.201601122

2116 Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C–F bond activation versus hydrogermylation T. Ahrens, M. Teltewskoi, M. Ahrens, T. Braun, R. Laubenstein Dalton Trans. 2016, 45, 17495–17507, 10.1039/C6DT03027K

2115 Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step J. Kohlmann, T. Braun, R. Laubenstein, R. Herrmann Chemistry - A European Journal 2017, 10.1002/chem.201700549

2100 Using Separable Nonnegative Matrix Factorization Techniques for the Analysis of Time-Resolved Raman Spectra R. Luce, P. Hildebrandt, U. Kuhlmann, J. Liesen Applied Spectroscopy 2016, 70, 1464–1475, 10.1177/0003702816662600

2092 Functional Graphene Nanomaterials Based Architectures: Biointeractions, Fabrications, and Emerging Biological Applications C. Cheng, S. Li, A. Thomas, N. A. Kotov, R. Haag Chemical Reviews 2017, 117, 1826–1914, 10.1021/acs.chemrev.6b00520

2076 Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation J. S. Völler, M. Dulic, U. I. M. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch ACS Central Science 2017, 3, 73–80, 10.1021/acscentsci.6b00339

2047 cis–trans-Amide isomerism of the 3,4-dehydroproline residue, the ‘unpuckered’ proline V. Kubyshkin, N. Budisa Beilstein Journal of Organic Chemistry 2016, 12, 589–593, 10.3762/bjoc.12.57

2046 Orthogonal Protein Translation Using Pyrrolysyl-tRNA Synthetases for Single- and Multiple-Noncanonical Amino Acid Mutagenesis T. Baumann, M. Exner, N. Budisa Advances in Biochemical Engineering/Biotechnology Springer International Publishing Switzerland Springer Berlin Heidelberg 2016,

2045 Photochemical formation of quinone methides from peptides containing modified tyrosine A. Husak, B. P. Noichl, T. Šumanovac Ramljak, M. Sohora, Org. Biomol. Chem. 2016, 14, 10894–10905, 10.1039/C6OB02191C

2044 Energetic contribution to both acidity and conformational stability in peptide models V. Kubyshkin, P. Durkin, N. Budisa New J. Chem. 2016, 40, 5209–5220, 10.1039/C5NJ03611A

2043 Incorporation of Amino Acids with Long-Chain Terminal Olefins into Proteins M. Exner, S. Köhling, J. Rivollier, S. Gosling, P. Srivastava, Z. Palyancheva, P. Herdewijn, M. P. Heck, J. Rademann, N. Budisa Molecules 2016, 21, 287– 10.3390/molecules21030287

2042 Congeneric lipases with improved catalytic activity and substrate accessibility / Engineering lipases with an expanded genetic code. A. De Simone, M. G. Hoesl, N. Budisa Applied Biocatalysis - From Fundamental Science to Industrial Applications Garabed Antranikian Wiley-VCH 2016,

2041 Construction of a polyproline structure with hydrophobic exterior using octahydroindole-2-carboxylic acid V. Kubyshkin, N. Budisa Org. Biomol. Chem. 2017, 15, 619–627, 10.1039/C6OB02306A

2040 One-Pot Synthesis of Unprotected Anomeric Glycosyl Thiols in Water for Glycan Ligation Reactions with Highly Functionalized Sugars S. Köhling, M. P. Exner, S. Nojoumi, J. Schiller, N. Budisa, J. Rademann Angewandte Chemie International Edition 2016, 55, 15510–15514, 10.1002/anie.201607228

2039 Design ofS-Allylcysteine in Situ Production and Incorporation Based on a Novel Pyrrolysyl-tRNA Synthetase Variant M. P. Exner, T. Kuenzl, T. M. T. To, Z. Ouyang, S. Schwagerus, M. G. Hoesl, C. P. R. Hackenberger, M. C. Lensen, S. Panke, N. Budisa ChemBioChem 2016, 18, 85–90, 10.1002/cbic.201600537

1962 Lanthipeptides: chemical synthesis versus in vivo biosynthesis as tools for pharmaceutical production E. L. Ongey, P. Neubauer Microbial Cell Factories 2016, 15, 10.1186/s12934-016-0502-y

1919 Leader Peptide-Free In Vitro Reconstitution of Microviridin Biosynthesis Enables Design of Synthetic Protease-Targeted Libraries E. Reyna-González, B. Schmid, D. Petras, R. D. Süssmuth, E. Dittmann Angewandte Chemie International Edition 2016, 55, 9398–9401, 10.1002/anie.201604345

1912 Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes C. Berg, T. Braun, R. Laubenstein, B. Braun Chem. Commun. 2016, 52, 3931–3934, 10.1039/C5CC10219G

1911 Dehydrogenation of cycloalkanes at rhodium complexes bearing fluorinated cyclopentadienyl ligands F. Liebau, T. Braun, B. Braun Journal of Fluorine Chemistry 2015, 180, 192–200, 10.1016/j.jfluchem.2015.09.014

1910 Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile R. Laubenstein, M. D. Şerb, U. Englert, G. Raabe, T. Braun, B. Braun Chem. Commun. 2016, 52, 1214–1217, 10.1039/C5CC08992A

1909 Remarkable reactivity of a rhodium(i) boryl complex towards CO₂and CS₂: isolation of a carbido complex S. I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann, R. Laubenstein Chem. Commun. 2015, 51, 14613–14616, 10.1039/C5CC05606C

1750 Toward intrinsically colored peptides: Synthesis and investigation of the spectral properties of methylated azatryptophans in tryptophan-cage mutants B. P. Noichl, P. M. Durkin, N. Budisa Biopolymers 2015, 104, 585–600, 10.1002/bip.22709

1749 Dendronylation: Residue-specific chemoselective attachment of oligoglycerol dendrimers on proteins with noncanonical amino acids Y. Ma, B. N. S. Thota, R. Haag, N. Budisa Bioorganic & Medicinal Chemistry Letters 2015, 25, 5247–5249, 10.1016/j.bmcl.2015.09.055

1748 Chemical Evolution of a Bacterial Proteome M. G. Hoesl, S. Oehm, P. Durkin, E. Darmon, L. Peil, H. R. Aerni, J. Rappsilber, J. Rinehart, D. Leach, D. Söll, N. Budisa Angewandte Chemie International Edition 2015, 54, 10030–10034, 10.1002/anie.201502868

1747 Chemische Evolution eines bakteriellen Proteoms M. G. Hoesl, S. Oehm, P. Durkin, E. Darmon, L. Peil, H. R. Aerni, J. Rappsilber, J. Rinehart, D. Leach, D. Söll, N. Budisa Angewandte Chemie 2015, 127, 10168–10172, 10.1002/ange.201502868

1746 Entropic Contribution of Elongation Factor P to Proline Positioning at the Catalytic Center of the Ribosome L. K. Doerfel, I. Wohlgemuth, V. Kubyshkin, A. L. Starosta, D. N. Wilson, N. Budisa, M. V. Rodnina Journal of the American Chemical Society 2015, 137, 12997–13006, 10.1021/jacs.5b07427

1714 Minimum information about a biosynthetic gene cluster M. H. Medema, R. Kottmann, P. Yilmaz, R. Süssmuth, and coworkers Nature Chemical Biology 2015, 11, 625–631, 10.1038/nchembio.1890

1704 Lipocarbazole, an efficient lipid peroxidation inhibitor anchored in the membrane G. Fabre, A. Hänchen, C. A. Calliste, K. Berka, S. Banala, M. Otyepka, R. D. Süssmuth, P. Trouillas Bioorganic & Medicinal Chemistry 2015, 23, 4866–4870, 10.1016/j.bmc.2015.05.031

1647 Synthesis and structure of rhodium(I) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds L. Zámostná, S. Sander, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, P. Kläring Dalton Trans. 2015, 10.1039/c5dt00819k

1587 Applying γ-Substituted Prolines in the Peptide: Polarity Contradicts Preorganization D. Dietz, V. Kubyshkin, N. Budisa ChemBioChem 2015, 16, 403–406, 10.1002/cbic.201402654

1586 Covalent Attachment of Cyclic TAT Peptides to GFP Results in Protein Delivery into Live Cells with Immediate Bioavailability N. Nischan, H. D. Herce, F. Natale, N. Bohlke, N. Budisa, M. C. Cardoso, C. P. R. Hackenberger Angewandte Chemie International Edition 2015, 54, 1950–1953, 10.1002/anie.201410006

1582 Coupling Bioorthogonal Chemistries with Artificial Metabolism: Intracellular Biosynthesis of Azidohomoalanine and Its Incorporation into Recombinant Proteins Y. Ma, H. Biava, R. Contestabile, N. Budisa, M. di Salvo Molecules 2014, 19, 1004–1022, 10.3390/molecules19011004

1581 Sense codon emancipation for proteome-wide incorporation of noncanonical amino acids: rare isoleucine codon AUA as a target for genetic code expansion N. Bohlke, N. Budisa FEMS Microbiology Letters 2014, 351, 133–144, 10.1111/1574-6968.12371

1579 Evolution of fluorinated enzymes: An emerging trend for biocatalyst stabilization H. Biava, N. Budisa Engineering in Life Sciences 2014, 14, 340–351, 10.1002/elsc.201300049

1554 Totalsynthese von Albicidin - eine Leitstruktur aus Xanthomonas albilineans fuer potente antibakterielle Gyrase-Inhibitoren J. Kretz, D. Kerwat, V. Schubert, S. Grätz, A. Pesic, S. Semsary, S. Cociancich, M. Royer, R. D. Süssmuth Angewandte Chemie 2015, 127, 1992–1996, 10.1002/ange.201409584

1553 Total Synthesis of Albicidin: A Lead Structure from Xanthomonas albilineans for Potent Antibacterial Gyrase Inhibitors J. Kretz, D. Kerwat, V. Schubert, S. Grätz, A. Pesic, S. Semsary, S. Cociancich, M. Royer, R. D. Süssmuth Angewandte Chemie International Edition 2015, 54, 1969–1973, 10.1002/anie.201409584

1515 [Ge(H)(2-C₆H₄PPh₂)₃] as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C₆H₄PPh₂)₃}] R. Herrmann, T. Braun, S. Mebs European Journal of Inorganic Chemistry 2014, 2014, 4826–4835, 10.1002/ejic.201402256

1514 C–H and C–F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics S. I. Kalläne, M. Teltewskoi, T. Braun, B. Braun Organometallics 2015, 150121145048004– 10.1021/om500952x

1513 Cationic Zinc Organyls as Precatalysts for Hydroamination Reactions M. A. Chilleck, L. Hartenstein, T. Braun, P. W. Roesky, B. Braun Chemistry - A European Journal 2015, 21, 2594–2602, 10.1002/chem.201405662

1512 Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks T. Ahrens, J. Kohlmann, M. Ahrens, T. Braun Chemical Reviews 2015, 115, 931–972, 10.1021/cr500257c

1467 Controlling fertilization and cAMP signaling in sperm by optogenetics V. Jansen, L. Alvarez, M. Balbach, T. Strünker, P. Hegemann, U. B. Kaupp, D. Wachten eLife 2015, 4, 10.7554/eLife.05161

1423 Catalytic Borylation of SCF₃-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective C-H Activation at the ortho-Position S. I. Kalläne, T. Braun Angewandte Chemie International Edition 2014, 53, 9311–9315, 10.1002/anie.201406424

1421 Synthesis and Structures of Fluorinated (β-Diketiminato)rhodium Complexes: Si-H Activation of Silanes at a Carbonyl Complex G. Meier, V. Steck, B. Braun, A. Eißler, R. Herrmann, M. Ahrens, R. Laubenstein, T. Braun European Journal of Inorganic Chemistry 2014, 2014, 2793–2808, 10.1002/ejic.201402087

1408 Stereochemistry and Conformation of Skyllamycin, a Non-Ribosomally Synthesized Peptide from Streptomyces sp. Acta 2897 V. Schubert, F. Di Meo, P. L. Saaidi, S. Bartoschek, H. P. Fiedler, P. Trouillas, R. D. Süssmuth Chemistry - A European Journal 2014, 20, 4948–4955, 10.1002/chem.201304562

1395 Versatile reactivity of a rhodium(I) boryl complex towards ketones and imines S. I. Kalläne, T. Braun, B. Braun, S. Mebs Dalton Transactions 2014, 43, 6786– 10.1039/c4dt00080c

1375 Biosynthetic rivalry of o-aminophenol-carboxylic acids initiates production of hemi-actinomycins in Streptomyces antibioticus I. Crnovcic, S. Semsary, J. Vater, U. Keller RSC Advances 2014, 4, 5065–5074, 10.1039/C3RA45661G

1374 MALDI-TOF mass spectrometry, an efficient technique for in situ detection and characterization of actinomycins J. Vater, I. Crnovcic, S. Semsary, U. Keller Journal of Mass Spectrometry 2014, 49, 210–222, 10.1002/jms.3329

1373 Cyclolization of D-Lysergic Acid Alkaloid Peptides J. Havemann, D. Vogel, B. Loll, U. Keller Chemistry & Biology 2014, 21, 146–155, 10.1016/j.chembiol.2013.11.008

1372 Occurrence and biosynthesis of C-demethylactinomycins in actinomycin-producing Streptomyces chrysomallus and Streptomyces parvulus I. Crnovcic, J. Vater, U. Keller The Journal of Antibiotics 2013, 66, 211–218, 10.1038/ja.2012.120

1369 The Actinomycin Biosynthetic Gene Cluster of Streptomyces chrysomallus: a Genetic Hall of Mirrors for Synthesis of a Molecule with Mirror Symmetry U. Keller, M. Lang, I. Crnovcic, F. Pfennig, F. Schauwecker Journal of Bacteriology 2010, 192, 2583–2595, 10.1128/JB.01526-09

1337 Biocatalytic synthesis of (2S)-5,5,5-trifluoroleucine and improved resolution into (2S,4S) and (2S,4R) diastereoisomers H. Biava, N. Budisa Tetrahedron Letters 2013, 54, 3662–3665, 10.1016/j.tetlet.2013.04.128

1336 Obtention of enantiomerically pure 5,5,5-trifluoro-l-isoleucine and 5,5,5-trifluoro-l-alloisoleucine H. Biava, N. Budisa Journal of Fluorine Chemistry 2013, 156, 372–377, 10.1016/j.jfluchem.2013.07.021

1326 Synthesis of Rhodium(I) Boryl Complexes: Catalytic N-H Activation of Anilines and Ammonia M. Teltewskoi, S. I. Kalläne, T. Braun, R. Herrmann European Journal of Inorganic Chemistry 2013, 2013, 5762–5768, 10.1002/ejic.201300972

1325 Neutral and Cationic Zinc Complexes with N- and S-Donor-Functionalized Cyclopentadienyl Ligands M. A. Chilleck, T. Braun, B. Braun, S. Mebs Organometallics 2014, 33, 551–560, 10.1021/om401076g

1324 Rhodium-Mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester T. Braun, M. Teltewskoi Efficient Preparations of Fluorine Compounds H. W. Roesky John Wiley & Sons 2012,

1323 Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C Me (CH ) NMe M. A. Chilleck, T. Braun, R. Herrmann, B. Braun Organometallics 2013, 32, 1067–1074, 10.1021/om301181e

1322 Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species M. Ahrens, G. Scholz, T. Braun, E. Kemnitz Angewandte Chemie International Edition 2013, 52, 5328–5332, 10.1002/anie.201300608

1321 Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions M. F. Kuehnel, D. Lentz, T. Braun Angewandte Chemie International Edition 2013, 52, 3328–3348, 10.1002/anie.201205260

1299 Ein Mikrogelbaukasten für die bioorthogonale Verkapselung und pH-gesteuerte Freisetzung von lebenden Zellen D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag Angewandte Chemie 2013, 125, 13780–13785, 10.1002/ange.201308005

1298 A Microgel Construction Kit for Bioorthogonal Encapsulation and pH-Controlled Release of Living Cells D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag Angewandte Chemie International Edition 2013, 52, 13538–13543, 10.1002/anie.201308005

1287 Building photoswitchable 3,4\'-AMPB peptides: Probing chemical ligation methods with reducible azobenzene thioesters G. Zeyat, K. Rück-Braun Beilstein Journal of Organic Chemistry 2012, 8, 890–896, 10.3762/bjoc.8.101

1157 Elimination Reactions of Esters in the Biosynthesis of Polyketides and Ribosomal Peptides B. Krawczyk, E. F. van Herwerden, H. S. Overkleeft, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9082–9084, 10.1002/anie.201304851

1154 Conformational investigation of antibiotic proximicin by X-ray structure analysis and quantum studies suggest a stretched conformation of this type of γ-peptide A. Denisiuk, V. Schubert, F. E. Wolter, E. Irran, P. Trouillas, R. D. Süssmuth Bioorganic & Medicinal Chemistry 2013, 21, 3582–3589, 10.1016/j.bmc.2013.02.051

1153 Alanine Scan of the Peptide Antibiotic Feglymycin: Assessment of Amino Acid Side Chains Contributing to Antimicrobial Activity A. Hänchen, S. Rausch, B. Landmann, L. Toti, A. Nusser, R. D. Süssmuth ChemBioChem 2013, 14, 625–632, 10.1002/cbic.201300032

1152 Characterization of the Biosynthetic Genes for 10,11-Dehydrocurvularin, a Heat Shock Response-Modulating Anticancer Fungal Polyketide from Aspergillus terreus Y. Xu, P. Espinosa-Artiles, V. Schubert, Y. M. Xu, W. Zhang, M. Lin, A. A. L. Gunatilaka, R. Sussmuth, I. Molnar Applied and Environmental Microbiology 2013, 79, 2038–2047, 10.1128/AEM.03334-12

1151 Total Synthesis of the Ribosomally Synthesized Linear Azole-Containing Peptide Plantazolicin A from Bacillus amyloliquefaciens S. Banala, P. Ensle, R. D. Süssmuth Angewandte Chemie International Edition 2013, 52, 9518–9523, 10.1002/anie.201302266

1137 Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates L. Zámostná, M. Ahrens, T. Braun Journal of Fluorine Chemistry 2013, 155, 132–142, 10.1016/j.jfluchem.2013.05.021

1136 α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen A. Eiβler, P. Kläring, F. Emmerling, T. Braun European Journal of Inorganic Chemistry 2013, 2013, 4775–4788, 10.1002/ejic.201300625

1069 Photolytic C-H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent T. Braun, B. Rabay, J. Falkenhagen Dalton Transactions 2013, 42, 8058–8065, 10.1039/c3dt33022b

1040 Calculation of the high pressure phase equilibrium in hyperbranched polymer systems with the Lattice-Cluster Theory K. Langenbach, S. Enders, C. Browarzik, D. Browarzik Journal of Chemical Thermodynamics 2013, 59, 107–113, 10.1016/j.jct.2012.12.002

1039 Development of an EOS based on lattice cluster theory for pure components K. Langenbach, S. Enders Fluid Phase Equilibria 2012, 331, 58–79, 10.1016/j.fluid.2012.06.022

1037 Liquid-liquid phase equilibria of hyperbranched polymers - experimental study and modelling C. Browarzik, D. Browarzik, S. Enders Fluid Phase Equilibria 2012, 328, 49–60, 10.1016/j.fluid.2012.05.018

1036 Phase Diagrams for Systems Containing Hyperbranched Polymers S. Enders, K. Langenbach, P. Schrader, T. Zeiner Polymers 2012, 4, 72–115, 10.3390/polym4010072

1032 Synthesis of Bi- and Tricyclic 1,2-Dihydroquinoline Derivatives from Arylamines and Alkynes by a Consecutive Zinc-Ammonium Salt Catalysis N. Purkait, S. Blechert Advanced Synthesis and Catalysis 2012, 354, 2079–2083, 10.1002/adsc.201200155

1030 Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction A. Luehl, H. P. Nayek, S. Blechert, P. W. Roesky Chemical Communications 2011, 47, 8280–8282, 10.1039/C1CC12461G

1029 Stabilizing Gold Adatoms by Thiophenyl Derivatives: A Possible Route toward Metal Redispersion B. Yang, Y. Pan, X. Lin, N. Nilius, H. J. Freund, C. Hulot, A. Giraud, S. Blechert, S. Tosoni, J. Sauer Journal of the American Chemical Society 2012, 134, 11161–11167, 10.1021/ja300304s

1028 A Microporous Binol-Derived Phosphoric Acid D. S. Kundu, J. Schmidt, C. Bleschke, A. Thomas, S. Blechert Angewandte Chemie International Edition 2012, 51, 5456–5459, 10.1002/anie.201109072

1027 Comparison of Decamethyldizincocene [(η5-Cp*)2Zn2] versus Decamethylzincocene [Cp*2Zn] and Diethylzinc Et2Zn As Precatalysts for the Intermolecular Hydroamination Reaction A. Luehl, L. Hartenstein, S. Blechert, P. W. Roesky Organometallics 2012, 20, 7109–7116, 10.1021/om300649q

1026 Effect of lattice-gas atoms on the adsorption behaviour of thioether molecules Y. Pan, B. Yang, C. Hulot, B. Siegfried, N. Nilius, H. J. Freund Physical Chemistry Chemical Physics 2012, 31, 10987–10993, 10.1039/C2CP41081H

1024 Polymeric Graphitic Carbon Nitride for Heterogeneous Photocatalysis X. Wang, S. Blechert, M. Antonietti ACS Catalysis 2012, 2, 1596–1606, 10.1021/cs300240x

1023 New catalysts with unsymmetrical N-heterocyclic carbene ligands J. Tornatzky, A. Kannenberg, S. Blechert Dalton Transactions 2012, 41, 8215–8225, 10.1039/C2DT30256J

908 Deuterium labeled peptides give insights into the directionality of class III lantibiotic synthetase LabKC B. Krawczyk, P. Ensle, W. Müller, R. D. Süssmuth Journal of the American Chemical Society 2012, 134, 9922–9925, 10.1021/ja3040224

903 The rise of the zinc age in homogeneous catalysis? S. Enthaler ACS Catalysis 2013, 3, 150–158, 10.1021/cs300685q

902 Nickel Complexes Modified by O,N,O'-Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for C-C Bond Formations C. I. Someya, E. Irran, S. Enthaler Asian Journal of Organic Chemistry 2012, 1, 322–326, 10.1002/ajoc.201200089

901 Straightforward Iron-catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes M. Haberberger, S. Enthaler Chemistry - An Asian Journal 2013, 8, 50–54, 10.1002/asia.201200931

886 Oxidative Coupling of Methane: Process Design, Development and Operation in a Mini-Plant Scale S. Stünkel, H. Trivedi, H. R. Godini, S. Jaso, N. Holst, S. Arndt, J. Steinbach, R. Schomäcker Chemie Ingenieur Technik 2012, 84, 1989–1996, 10.1002/cite.201200052

844 Activation and Coordination of Ammonia at [Cp*Ir(H)2]: NMR and Matrix Isolation Studies T. Braun, C. Limberg, A. K. Jungton, C. Herwig Chemistry - A European Journal 2012, 18, 10009–10013, 10.1002/chem.201201295

818 Synthesis, reactivity and structures of iridium tetrafluoropyridyl complexes: Ammonia coordination and activation T. Braun, A. K. Jungton, P. Kläring, A. Eißler Zeitschrift für Anorganische und Allgemeine Chemie 2012, 638, 505–511, 10.1002/zaac.201100440