2265 Four-electron reduction of dioxygen to water by a trinuclear copper complex X. Engelmann, E. R. Farquhar, J. England, K. Ray Inorganica Chimica Acta 2017, 10.1016/j.ica.2017.11.014
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2264 A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2M′] Complexes in Oxidation Reactions X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray Angewandte Chemie 2017, 129, 303–307, 10.1002/ange.201607611
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2263 Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex B. Wang, Y. M. Lee, W. Y. Tcho, S. Tussupbayev, S. T. Kim, Y. Kim, M. S. Seo, K. B. Cho, Y. Dede, B. C. Keegan, T. Ogura, S. H. Kim, T. Ohta, M. H. Baik, K. Ray, J. Shearer, W. Nam Nature Communications 2017, 8, 14839– 10.1038/ncomms14839
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2262 A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand I. Monte Pérez, X. Engelmann, Y. M. Lee, M. Yoo, E. Kumaran, E. R. Farquhar, E. Bill, J. England, W. Nam, M. Swart, K. Ray Angewandte Chemie International Edition 2017, 56, 14384–14388, 10.1002/anie.201707872
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2162 Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex I. Monte-Pérez, S. Kundu, A. Chandra, K. E. Craigo, P. Chernev, U. Kuhlmann, H. Dau, P. Hildebrandt, C. Greco, C. Van Stappen, N. Lehnert, K. Ray Journal of the American Chemical Society 2017, 139, 15033–15042, 10.1021/jacs.7b07127
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2004 Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species T. Corona, L. Ribas, M. Rovira, E. R. Farquhar, X. Ribas, K. Ray, A. Company Angewandte Chemie International Edition 2016, 55, 14005–14008, 10.1002/anie.201607238
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2003 A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions S. Kundu, P. Chernev, X. Engelmann, C. S. Chung, H. Dau, E. Bill, J. England, W. Nam, K. Ray Dalton Trans. 2016, 45, 14538–14543, 10.1039/c6dt01815g
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2002 Changing the chemical and physical properties of high valent heterobimetallic bis-(μ-oxido) Cu–Ni complexes by ligand effects M. C. Kafentzi, M. Orio, M. Réglier, S. Yao, U. Kuhlmann, P. Hildebrandt, M. Driess, A. J. Simaan, K. Ray Dalton Trans. 2016, 45, 15994–16000, 10.1039/c6dt02391f
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2001 Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes S. Hong, Y. M. Lee, K. Ray, W. Nam Coordination Chemistry Reviews 2016, 10.1016/j.ccr.2016.07.006
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2000 Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes X. Engelmann, I. Monte-Pérez, K. Ray Angewandte Chemie International Edition 2016, 55, 7632–7649, 10.1002/anie.201600507
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1953 A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O)2M′] Complexes in Oxidation Reactions X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray Angewandte Chemie International Edition 2016, 10.1002/anie.201607611
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1841 An iron(II) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg Dalton Trans. 2016, 45, 2989–2996, 10.1039/C5DT04266F
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1752 Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions M. Goswami, V. Lyaskovskyy, S. R. Domingos, W. J. Buma, S. Woutersen, O. Troeppner, I. Ivanović-Burmazović, H. Lu, X. Cui, X. P. Zhang, E. J. Reijerse, S. DeBeer, M. M. van Schooneveld, F. F. Pfaff, K. Ray, B. de Bruin Journal of the American Chemical Society 2015, 137, 5468–5479, 10.1021/jacs.5b01197
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1751 Reactivity of a Nickel(II) Bis(amidate) Complex with -Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species T. Corona, F. F. Pfaff, F. Acuña-Parés, A. Draksharapu, C. J. Whiteoak, V. Martin-Diaconescu, J. Lloret-Fillol, W. R. Browne, K. Ray, A. Company Chemistry - A European Journal 2015, 21, 15029–15038, 10.1002/chem.201501841
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1636 High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting K. Ray, F. Heims, M. Schwalbe, W. Nam Current Opinion in Chemical Biology 2015, 25, 159–171, 10.1016/j.cbpa.2015.01.014
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1501 An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties I. Monte-Pérez, S. Kundu, K. Ray Zeitschrift für anorganische und allgemeine Chemie 2015, 641, 78–82, 10.1002/zaac.201400389
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1500 Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes S. L. Abram, I. Monte-Pérez, F. F. Pfaff, E. R. Farquhar, K. Ray Chemical Communications 2014, 50, 9852– 10.1039/C4CC03754E
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1499 Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups S. Kundu, E. Miceli, E. R. Farquhar, K. Ray Dalton Transactions 2014, 43, 4264– 10.1039/C3DT52644E
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1498 Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions S. Hong, F. F. Pfaff, E. Kwon, Y. Wang, M. S. Seo, E. Bill, K. Ray, W. Nam Angewandte Chemie International Edition 2014, 53, 10403–10407, 10.1002/anie.201405874
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1497 Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions K. Ray, F. F. Pfaff, B. Wang, W. Nam Journal of the American Chemical Society 2014, 136, 13942–13958, 10.1021/ja507807v
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1353 A High-Valent Heterobimetallic [Cu(III) (μ-O) Ni(III)]2+ Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie International Edition 2013, 52, 5622–5626, 10.1002/anie.201300861
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1282 Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11 K. Ray, F. Heims, F. F. Pfaff European Journal of Inorganic Chemistry 2013, 2013, 3784–3807, 10.1002/ejic.201300223
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1280 A High-Valent Heterobimetallic [Cu (μ-O) Ni ] Core with Nucleophilic Oxo Groups S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray Angewandte Chemie 2013, 125, 5732–5736, 10.1002/ange.201300861
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1279 Redox Non-Innocence of a N-Heterocyclic Nitrenium Cation Bound to a Nickel–Cyclam Core F. Heims, F. F. Pfaff, S. L. Abram, E. R. Farquhar, M. Bruschi, C. Greco, K. Ray Journal of the American Chemical Society 2014, 136, 582–585, 10.1021/ja4099559
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1147 Access to a CuII–O–CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity P. Haack, A. Kärgel, C. Greco, J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg Journal of the American Chemical Society 2013, 135, 16148–16160, 10.1021/ja406721a
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982 Nonheme oxoiron( IV ) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity D. Wang, K. Ray, M. J. Collins, E. R. Farquhar, J. R. Frisch, L. Gomez, T. A. Jackson, M. Kerscher, A. Waleska, P. Comba, M. Costas, L. Que, Jr. Chemical Science 2013, 4, 282–291, 10.1039/C2SC21318D
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979 O-O Bond Formation Mediated by a Hexanuclear Iron Complex Supported on a Stannoxane Core S. Kundu, E. Matito, S. Walleck, F. F. Pfaff, F. Heims, B. Rabay, J. M. Luis, A. Company, B. Braun, T. Glaser, K. Ray Chemistry - A European Journal 2012, 10, 2787–2791, 10.1002/chem.201102326
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978 Spectroscopic capture and reactivity of S = 1/2 nickel(III)–oxygen intermediates in the reaction of a NiII-salt with mCPBA F. F. Pfaff, F. Heims, S. Kundu, S. Mebs, K. Ray Chemical Communications 2012, 48, 3730–3732, 10.1039/C2CC30716B
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977 The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes J. Hohenberger, K. Ray, K. Meyer Nature Communications 2012, 3, 720–733, 10.1038/ncomms1718
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976 Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System F. Heims, V. Mereacre, A. Ciancetta, S. Mebs, A. K. Powell, C. Greco, K. Ray European Journal of Inorganic Chemistry 2012, 29, 4565–4569, 10.1002/ejic.201200156
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975 Metal-oxo-mediated O-O bond formation reactions in chemistry and biology S. Kundu, M. Schwalbe, K. Ray Bioinorganic Reaction Mechanisms 2012, 8, 41–57, 10.1515/irm-2012-0004
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974 Lewis-acid Trapping of an Elusive Copper-Tosylnitrene Intermediate Using Scandium Triflate S. Kundu, E. Miceli, E. Farquhar, F. F. Pfaff, U. Kuhlmann, P. Hildebrandt, B. Braun, C. Greco, K. Ray Journal of the American Chemical Society 2012, 134, 14710–14713, 10.1021/ja306674h
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671 An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions F. Pfaff, S. Kundu, M. Risch, S. Pandian, F. Heims, I. Pryjoms-Ray, P. Haack, R. Metzinger, E. Bill, H. Dau, P. Comba, K. Ray Angewandte Chemie International Edition 2011, 50, 1711–1715, 10.1002/anie.201005869
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494 Dinuclear Copper Complexes Based on Parallel ß-Diiminato Binding Sites and their Reactions with O2: Evidence for a Cu-O-Cu Entity P. Haack, C. Limberg, K. Ray, B. Braun, U. Kuhlmann, P. Hildebrandt, C. Herwig Inorganic Chemistry 2011, 50, 2133–2142, 10.1021/ic101249k
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