2302 Thermal O–H Bond Activation of Water As Mediated by Heteronuclear [Al2Mg2O5]•+: Evidence for Oxygen-Atom Scrambling C. Geng, J. Li, T. Weiske, H. Schwarz Journal of the American Chemical Society 2018, 140, 9275–9281, 10.1021/jacs.8b05618
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2297 Experimentelle Bestimmung des aktiven Zentrums im heteronuklearen Redox-System [AlVOx]+./CO/N2O (x=3, 4) durch Gasphasen-Infrarotspektroskopie S. Debnath, H. Knorke, W. Schöllkopf, S. Zhou, K. R. Asmis, H. Schwarz Angewandte Chemie 2018, 130, 7570–7574, 10.1002/ange.201804056
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2296 Experimental Identification of the Active Site in the Heteronuclear Redox Couples [AlVOx]+./CO/N2O (x=3, 4) by Gas-Phase IR Spectroscopy S. Debnath, H. Knorke, W. Schöllkopf, S. Zhou, K. R. Asmis, H. Schwarz Angewandte Chemie International Edition 2018, 57, 7448–7452, 10.1002/anie.201804056
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2295 Über die Ursachen der deutlich unterschiedlichen Reaktivität von Ruthenium unter den [MO]+/CH4-Systemen (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 130, 6039–6043, 10.1002/ange.201800173
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2294 On the Origin of the Distinctly Different Reactivity of Ruthenium in [MO]+/CH4Systems (M=Fe, Ru, Os) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 5934–5937, 10.1002/anie.201800173
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2256 Direkte Umwandlung von Methan zu protoniertem Formaldehyd bei Raumtemperatur in der Gasphase: Zur Rolle von Quecksilber unter den Oxidkationen der Zinktriade L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie 2018, 130, 3306–3310, 10.1002/ange.201712405
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2255 Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2018, 57, 3251–3255, 10.1002/anie.201712405
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2198 Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+ M. Firouzbakht, N. J. Rijs, M. Schlangen, M. Kaupp, H. Schwarz Topics in Catalysis 2018, 61, 575–584, 10.1007/s11244-018-0903-8
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2148 Spin-Selective, Competitive Hydrogen-Atom Transfer versus CH2O-Generation from the CH4/[ReO4]+Couple at Ambient Conditions S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 23, 17469–17472, 10.1002/chem.201704892
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2147 Electronic Effects on Room-Temperature, Gas-Phase C–H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge H. Schwarz, S. Shaik, J. Li Journal of the American Chemical Society 2017, 139, 17201–17212, 10.1021/jacs.7b10139
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2145 Elektronische Ursache konkurrierender Mechanismen bei der thermischen Aktivierung von Methan durch das heteronukleare Clusteroxid [Al2ZnO4].+ S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 129, 14486–14990, 10.1002/ange.201704979
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2144 Electronic Origin of the Competitive Mechanisms in the Thermal Activation of Methane by the Heteronuclear Cluster Oxide [Al2ZnO4].+ S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 14297–14300, 10.1002/anie.201704979
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2143 Ursachen der unterschiedlichen Reaktivität von [AlCeOx]+(x=2-4) gegenüber Methan in Abhängigkeit vom Sauerstoffgehalt S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 129, 424–428, 10.1002/ange.201610424
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2142 On the Electronic Origin of Remarkable Ligand Effects on the Reactivities of [NiL]+Complexes (L=C6H5, C5H4N, CN) towards Methane S. Zhou, M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 23, 14430–14433, 10.1002/chem.201703767
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2141 Ménage-à-trois: single-atom catalysis, mass spectrometry, and computational chemistry H. Schwarz Catal. Sci. Technol. 2017, 7, 43–4314, 10.1039/c6cy02658c
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2139 Metal-Dependent Strengthening and Weakening of M−H and M−C Bonds by an Oxo Ligand: Thermal Gas-Phase Activation of Methane by [OMH]+and [MH]+(M=Mo, Ti) M. Firouzbakht, S. Zhou, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2017, 23, 12346–12352, 10.1002/chem.201701615
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2134 Control of Product Distribution and Mechanism by Ligation and Electric Field in the Thermal Activation of Methane L. Yue, J. Li, S. Zhou, X. Sun, M. Schlangen, S. Shaik, H. Schwarz Angewandte Chemie International Edition 2017, 56, 10219–10223, 10.1002/anie.201703485
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2133 Steuerung der Produktverteilung und der Mechanismen der thermischen Aktivierung von Methan durch Ligandeneffekte und elektrische Felder L. Yue, J. Li, S. Zhou, X. Sun, M. Schlangen, S. Shaik, H. Schwarz Angewandte Chemie 2017, 129, 10353–10357, 10.1002/ange.201703485
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2132 Metallfreier, durch [Si2Ox].+(x=2-5) katalysierter Sauerstofftransfer im N2O/CO-Redoxpaar bei Raumtemperatur X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 129, 10122–10126, 10.1002/ange.201703453
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2131 Metal-Free, Room-Temperature Oxygen-Atom Transfer in the N2O/CO Redox Couple as Catalyzed by [Si2Ox].+(x=2-5) X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 9990–9993, 10.1002/anie.201703453
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2118 Sequential Gas-Phase Activation of Carbon Dioxide and Methane by [Re(CO)2]+: The Sequence of Events Matters! S. Zhou, J. Li, M. Firouzbakht, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2017, 139, 6169–6176, 10.1021/jacs.7b01255
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2112 Tuning the oxidative power of free iron–sulfur clusters S. M. Lang, S. Zhou, H. Schwarz Phys. Chem. Chem. Phys. 2017, 19, 8055–8060, 10.1039/c7cp00023e
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2110 On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x]+/CH4(x=0-3) Couples S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2017, 129, 2997–3000, 10.1002/ange.201611826
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2109 On the Origin of Reactivity Enhancement/Suppression upon Sequential Ligation: [Re(CO)x]+/CH4(x=0-3) Couples S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 2951–2954, 10.1002/anie.201611826
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2095 Gas-phase reactions of cationic molybdenum and tungsten monoxide with ethanol: a combined experimental/computational exercise P. González-Navarrete, M. Schlangen, H. Schwarz Structural Chemistry 2016, 28, 403–413, 10.1007/s11224-016-0862-2
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2067 Thermal Methane Activation by the Metal-Free Cluster Cation [Si2O4].+ X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2017, 23, 1498–1501, 10.1002/chem.201605496
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2057 Metal-mediated activation of carbon dioxide in the gas phase: Mechanistic insight derived from a combined experimental/computational approach H. Schwarz Coordination Chemistry Reviews 2017, 334, 112–123, 10.1016/j.ccr.2016.03.009
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2056 Electrostatic and Charge-Induced Methane Activation by a Concerted Double C–H Bond Insertion C. Geng, J. Li, T. Weiske, M. Schlangen, S. Shaik, H. Schwarz Journal of the American Chemical Society 2017, 139, 1684–1689, 10.1021/jacs.6b12514
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2054 Striking Doping Effects on Thermal Methane Activation Mediated by the Heteronuclear Metal Oxides [XAlO4].+(X=V, Nb, and Ta) X. N. Wu, J. Li, M. Schlangen, S. Zhou, P. González-Navarrete, H. Schwarz Chemistry - A European Journal 2017, 23, 788–792, 10.1002/chem.201605226
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1970 Zum Ursprung der effizienten thermischen Chemisorption von Methan durch den heteronuklearen Metalloxidcluster [Al2TaO5]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 15090–15094, 10.1002/ange.201608999
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1969 Thermische Dehydrierung von Methan durch [ReN]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 15085–15089, 10.1002/ange.201607960
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1968 Thermische Methanaktivierung durch [Si2O5].+und [Si2O5H2].+: Reaktivitätssteigerung durch Hydrierung X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 13540–13543, 10.1002/ange.201607864
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1967 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC]+with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie 2016, 128, 13266–13269, 10.1002/ange.201606707
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1966 Effiziente, thermische Aktivierung von Methan durch TaN+unter C-N-Kupplung S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 11851–11855, 10.1002/ange.201606259
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1965 Die Chemie von [AuO]+/CH4in der Gasphase: Selektive Sauerstoffatom-Übertragung auf, statt Wasserstoffatom-Abstraktion von Methan S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 11036–11039, 10.1002/ange.201605259
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1964 Spinabhängige, thermische Aktivierung von Methan durch den geschlossenschaligen Cluster [TaO3]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 7374–7377, 10.1002/ange.201601965
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1963 Thermal Activation of Methane by [HfO].+and [XHfO]+(X=F, Cl, Br, I) and the Origin of a Remarkable Ligand Effect S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 7685–7688, 10.1002/anie.201602312
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1961 Unexpected Mechanistic Variants in the Thermal Gas-Phase Activation of Methane H. Schwarz, P. González-Navarrete, J. Li, M. Schlangen, X. Sun, T. Weiske, S. Zhou Organometallics 2017, 36, 8–17, 10.1021/acs.organomet.6b00372
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1958 On the Origin of the Remarkably Variable Reactivities of [AlCeOx]+(x=2-4) towards Methane as a Function of Oxygen Content S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2017, 56, 413–416, 10.1002/anie.201610424
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1950 Thermal Dehydrogenation of Methane by [ReN]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 14863–14866, 10.1002/anie.201607960
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1949 The Origin of the Efficient, Thermal Chemisorption of Methane by the Heteronuclear Metal-Oxide Cluster [Al2TaO5]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 14867–14871, 10.1002/anie.201608999
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1948 Mechanistic aspects of CO2 activation mediated by phenyl yttrium cation: A combined experimental/theoretical study M. Firouzbakht, M. Schlangen, M. Kaupp, H. Schwarz Journal of Catalysis 2016, 343, 68–74, 10.1016/j.jcat.2015.09.012
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1943 Thermal Methane Activation by [Si2O5].+and [Si2O5H2].+: Reactivity Enhancement by Hydrogenation X. Sun, S. Zhou, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 13345–13348, 10.1002/anie.201607864
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1942 Hidden Hydride Transfer as a Decisive Mechanistic Step in the Reactions of the Unligated Gold Carbide [AuC]+with Methane under Ambient Conditions J. Li, S. Zhou, M. Schlangen, T. Weiske, H. Schwarz Angewandte Chemie International Edition 2016, 55, 13072–13075, 10.1002/anie.201606707
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1936 Efficient Room-Temperature Methane Activation by the Closed-Shell, Metal-Free Cluster [OSiOH]+: A Novel Mechanistic Variant X. Sun, S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 14257–14263, 10.1002/chem.201601981
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1935 Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions J. Li, S. Zhou, J. Zhang, M. Schlangen, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 138, 11368–11377, 10.1021/jacs.6b07246
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1934 Efficient Room-Temperature Activation of Methane by TaN+under C−N Coupling S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 11678–11681, 10.1002/anie.201606259
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1933 The Unique Gas-Phase Chemistry of the [AuO]+/CH4Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 10877–10880, 10.1002/anie.201605259
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1927 On the Activation of Methane and Carbon Dioxide by [HTaO]+and [TaOH]+in the Gas Phase: A Mechanistic Study M. Firouzbakht, N. J. Rijs, P. González-Navarrete, M. Schlangen, M. Kaupp, H. Schwarz Chemistry - A European Journal 2016, 22, 10581–10589, 10.1002/chem.201601339
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1920 Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2]+(X, Y = Al, Si, Mg): Competition between Proton-Coupled Electron Transfer and Hydrogen-Atom Transfer J. Li, S. Zhou, J. Zhang, M. Schlangen, T. Weiske, D. Usharani, S. Shaik, H. Schwarz Journal of the American Chemical Society 2016, 138, 7973–7981, 10.1021/jacs.6b03798
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1918 Thermische Aktivierung von Methan durch [HfO].+und [XHfO]+(X=F, Cl, Br, I): ein außergewöhnlicher Ligandeneffekt und dessen Ursache S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 7816–7819, 10.1002/ange.201602312
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1917 Spin-Selective Thermal Activation of Methane by Closed-Shell [TaO3]+ S. Zhou, J. Li, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 7257–7260, 10.1002/anie.201601965
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1913 Differences and Commonalities in the Gas-Phase Reactions of Closed-Shell Metal Dioxide Clusters [MO2]+(M=V, Nb, and Ta) with Methane S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 7225–7228, 10.1002/chem.201600498
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1846 Bond Activation by Metal–Carbene Complexes in the Gas Phase S. Zhou, J. Li, M. Schlangen, H. Schwarz Accounts of Chemical Research 2016, 49, 494–502, 10.1021/acs.accounts.5b00023
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1845 Mechanistic Aspects of the Holmium-mediated, Reciprocal Hydrogen/Sulfur Exchange in the Gas Phase: C₆H₅CH₃ + CH₂S → C₆H₅CHS + CH₄ S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 4336–4339, 10.1002/chem.201600061
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1840 On the Origin of Room-temperature, Au+-mediated Coupling of a Methylene Ligand with H2. Implications for the Mechanism of Methane Dehydrogenation. J. Li , S. Zhou, M. Schlangen, T. Weiske, H. Schwarz ChemistrySelect 2016, 1, 444–447, 10.1002/slct.201600073
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1839 Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO]+Complexes with Fluoromethanes (CH(4–n)Fn,n= 1–3) N. J. Rijs, P. González-Navarrete, M. Schlangen, H. Schwarz Journal of the American Chemical Society 2016, 138, 3125–3135, 10.1021/jacs.5b12972
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1792 Breaking and Making of Carbon-Carbon Bonds by Lanthanides and Third-Row Transition Metals S. Zhou, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2016, 22, 3073–3076, 10.1002/chem.201504571
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1791 Unravelling Mechanistic Aspects of the Gas-Phase Ethanol Conversion: An Experimental and Computational Study on the Thermal Reactions of MO2+(M=Mo, W) with Ethanol P. González-Navarrete, M. Schlangen, X. N. Wu, H. Schwarz Chemistry - A European Journal 2016, 22, 3077–3083, 10.1002/chem.201504929
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1786 Zur Rolle der Elektronenstruktur des heteronuklearen Oxidclusters [Ga2Mg2O5].+ in der thermischen Aktivierung von Methan und Ethan: ein ungewöhnlicher Dotierungseffekt J. Li, X. N. Wu, M. Schlangen, S. Zhou, P. González-Navarrete, S. Tang, H. Schwarz Angewandte Chemie 2015, 127, 5163–5167, 10.1002/ange.201412441
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1785 Zum Mechanismus des Wasserstoffatomtransfers von Wasser auf den heteronuklearen Oxidcluster [Ga2Mg2O5] .+ : außergewöhnliche Effekte der elektronischen Struktur J. Li, S. Zhou, X. N. Wu, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie 2015, 127, 12028–12032, 10.1002/ange.201505336
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1784 Deutlich unterschiedliche Mechanismen der Wasserstoffatomabstraktion aus Methan und Wasser durch den heteronuklearen Oxidcluster [Ga2MgO4] .+ J. Li, X. N. Wu, S. Zhou, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie 2015, 127, 12472–12477, 10.1002/ange.201503763
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1771 Efficient Room-Temperature, Au+ -Mediated Coupling of a Carbene Ligand with Methane To Generate C2Hx (x=4, 6) S. Zhou, J. Li, X. N. Wu, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2016, 55, 441–444, 10.1002/anie.201509320
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1770 Au+ -vermittelte, effiziente Kupplung eines Carbenliganden mit Methan: Bildung von C2Hx (x=4, 6) bei Raumtemperatur S. Zhou, J. Li, X. N. Wu, M. Schlangen, H. Schwarz Angewandte Chemie 2016, 128, 452–455, 10.1002/ange.201509320
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1715 Correction to Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal-1,10- Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 87, 11601–11601, 10.1021/acs.analchem.5b03989
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1701 Distinct Mechanistic Differences in the Hydrogen-Atom Transfer from Methane and Water by the Heteronuclear Oxide Cluster [Ga2MgO4] J. Li, X. N. Wu, S. Zhou, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 54, 12298–12302, 10.1002/anie.201503763
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1700 Effect of Adduct Formation with Molecular Nitrogen on the Measured Collisional Cross Sections of Transition Metal–1,10-Phenanthroline Complexes in Traveling Wave Ion-Mobility Spectrometry: N Is Not Always an “Inert” Buffer Gas N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Analytical Chemistry 2015, 87, 9769–9776, 10.1021/acs.analchem.5b01985
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1694 “Stripping” the Carbon Atom of Methyl Halide by a Cationic Holmium Complex: A Gas-Phase Study S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 21, 14305–14308, 10.1002/chem.201502183
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1693 On the Mechanisms of Hydrogen-Atom Transfer from Water to the Heteronuclear Oxide Cluster [Ga2Mg2O5].+ : Remarkable Electronic Structure Effects J. Li, S. Zhou, X. N. Wu, S. Tang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2015, 54, 11861–11864, 10.1002/anie.201505336
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1688 Doping Effects in Cluster-Mediated Bond Activation H. Schwarz Angewandte Chemie International Edition 2015, 54, 10090–10100, 10.1002/anie.201500649
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1687 Carbon-Atom Extrusion from Halobenzenes and Its Coupling with a Methylene Ligand to Form Acetylene S. Zhou, M. Schlangen, J. Li, X. N. Wu, H. Schwarz Chemistry - A European Journal 2015, 21, 9629–9631, 10.1002/chem.201501871
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1678 Ligand-Controlled CO2 Activation Mediated by Cationic Titanium Hydride Complexes, [LTiH]+ ( L= Cp2 , O) S. Y. Tang, N. J. Rijs, J. Li, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 8483–8490, 10.1002/chem.201500722
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1677 Thermal hydrogen-atom transfer from methane: A mechanistic exercise H. Schwarz Chemical Physics Letters 2015, 629, 91–101, 10.1016/j.cplett.2015.04.022
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1653 Activation of Methane and Carbon Dioxide Mediated by Transition-Metal Doped Magnesium Oxide Clusters [MMgO]+/o/- (M=Sc-Zn) J. Li, P. González-Navarrete, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 7780–7789, 10.1002/chem.201500715
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1644 On the Role of the Electronic Structure of the Heteronuclear Oxide Cluster [Ga2Mg2O5].+ in the Thermal Activation of Methane and Ethane: An Unusual Doping Effect J. Li, X. N. Wu, M. Schlangen, S. Zhou, P. González-Navarrete, S. Tang, H. Schwarz Angewandte Chemie International Edition 2015, 54, 5074–5078, 10.1002/anie.201412441
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1643 Mechanistic aspects of the gas-phase coupling of thioanisole and chlorobenzene to dibenzothiophene catalyzed by atomic Ho S. Zhou, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. 2015, 17, 9564–9568, 10.1039/c5cp01038a
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1484 Mechanistic Aspects of the Gas-Phase Reactions of Halobenzenes with Bare Lanthanide Cations: A Combined Experimental/Theoretical Investigation S. Zhou, M. Schlangen, H. Schwarz Chemistry - A European Journal 2015, 21, 2123–2131, 10.1002/chem.201405964
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1444 Highly regioselective hydride transfer, oxidative dehydrogenation, and hydrogen-atom abstraction in the thermal gas-phase chemistry of [Zn(OH)]+/C3H8 X. N. Wu, H. T. Zhao, J. Li, M. Schlangen, H. Schwarz Phys. Chem. Chem. Phys. 2014, 16, 26617–26623, 10.1039/c4cp02139h
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1432 Mechanisms of Metal-mediated C−N Coupling Processes: A Synergistic Relationship Between Gas-phase Experiments and Computational Chemistry H. Schwarz, R. Kretschmer, M. Schlangen Understanding Organometallic Reaction Mechanisms and Catalysis Ananikov, Valentine Wiley-VCH 2014,
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1426 How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane? H. Schwarz Israel Journal of Chemistry 2014, 54, 1413–1431, 10.1002/ijch.201300134
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1406 On divorcing isomers, dissecting reactivity, and resolving mechanisms of propane C—H and aryl C—X (X = halogen) bond activations mediated by a ligated copper(III) oxo complex N. J. Rijs, T. Weiske, M. Schlangen, H. Schwarz Chemical Physics Letters 2014, 608, 408–424, 10.1016/j.cplett.2014.05.005
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1399 Thermal Ethane Activation by Bare [V2O5]+ and [Nb2O5]+ Cluster Cations: on the Origin of Their Different Reactivities X. N. Wu, S. Y. Tang, H. T. Zhao, T. Weiske, M. Schlangen, H. Schwarz Chemistry - A European Journal 2014, 20, 6672–6677, 10.1002/chem.201402055
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1121 Thermal Activation of Ammonia by Transition-Metal Hydroxide Cations R. Kretschmer, M. Schlangen, H. Schwarz ChemPlusChem 2013, 78, 952–958, 10.1002/cplu.201300138
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1098 Einfache und doppelte N-H-Aktivierung in NH3 durch [Al2O3].+ : Erzeugung des Aminylradikals und von Nitren bei Raumtemperatur R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie 2013, 125, 9691–9695, 10.1002/ange.201302506
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1097 Single and Double N-H Bond Activation of Ammonia by [Al2O3 ].+ : Room Temperature Formation of the Aminyl Radical and Nitrene R. Kretschmer, Z. C. Wang, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 9513–9517, 10.1002/anie.201302506
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1096 Thermal Methane Activation by a Binary V-Nb Transition-Metal Oxide Cluster Cation: A Further Example for the Crucial Role of Oxygen-Centered Radicals Z. C. Wang, J. W. Liu, M. Schlangen, T. Weiske, D. Schröder, J. Sauer, H. Schwarz Chemistry - A European Journal 2013, 19, 11496–11501, 10.1002/chem.201302133
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1095 Isomer-Selective Thermal Activation of Methane in the Gas Phase by [HMO]+ and [M(OH)]+ (M=Ti and V) R. Kretschmer, M. Schlangen, H. Schwarz Angewandte Chemie International Edition 2013, 52, 6097–6101, 10.1002/anie.201300900
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1067 Mechanistic Aspects of Gas-Phase Hydrogen-Atom Transfer from Methane to [CO].+ and [SiO].+: Why Do They Differ? H. Schwarz, N. Dietl, A. Troiani, M. Schlangen, O. Ursini, G. Angelini, Y. Apeloig, G. de Petris Chemistry - A European Journal 2013, 19, 6662–6669, 10.1002/chem.201204157
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1016 Structure and Chemistry of the Heteronuclear Oxo-Cluster [VPO4].+: A Model System for the Gas-Phase Oxidation of Small Hydrocarbons H. Schwarz, N. Dietls, T. Wende, K. Chen, L. Jiang, M. Schlangen, X. Zhao, K. R. Asmis Journal of the American Chemical Society 2013, 135, 3711–3721, 10.1021/ja400198y
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945 Radical detection in harsh environments by means of laserinduced fluorescence using a single bidirectional optical fiber H. Schwarz, R. Schlögl, R. Horn Applied Physics B 2012, 109, 19–26, 10.1007/s00340-012-5172-9
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935 C-N coupling in the gas-phase reactions of ammonia and [M(CH)]+ (M = Ni, Pd, Pt): a combined experimental/computational exercise H. Schwarz, R. Kretschmer, M. Schlangen Dalton Transactions 2013, 42, 4153–4162, 10.1039/c3dt32596b
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863 On the Origin of the Surprisingly Sluggish Redox Reaction of the N2O/CO Couple Mediated by [Y2O2]+. and [YAlO2]+. Cluster Ions in the Gas Phase H. Schwarz, J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He Angewandte Chemie International Edition 2013, 52, 1226–1230, 10.1002/anie.201208559
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855 Effects of Ligands, Cluster Size, and Charge State in Gas-Phase Catalysis: A Happy Marriage of Experimental and Computational Studies H. Schwarz, M. Schlangen Catalysis Letters 2012, 142, 1265–1278, 10.1007/s10562-012-0892-3
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854 Mechanistic Studies on the Gas-Phase Dehydrogenation of Alkanes at Cyclometalated Platinum Complexes H. Schwarz, B. Butschke Chemistry - A European Journal 2012, 18, 14055–14062, 10.1002/chem.201201652
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820 Thermal Reactions of YAlO3+• with Methane: Increasing the Reactivity of Y2O3+• and the Selectivity of Al2O3+• by Doping H. Schwarz, J. B. Ma, Z. C. Wang, M. Schlangen, S. G. He Angewandte Chemie International Edition 2012, 51, 5991–5994, 10.1002/anie.201201698
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819 A computational study on the intriguing mechanisms of the gas-phase thermal activation of methane by bare [Ni(H)(OH)]+ O. Lakuntza, J. M. Matxain, F. Ruipérez, M. Besora, F. Maseras, J. M. Ugalde, M. Schlangen, H. Schwarz Physical Chemistry Chemical Physics 2012, 14, 9306–9310, 10.1039/c2cp23502a
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814 Thermal Ammonia Activation by Cationic Transition-Metal Hydrides of the First Row – Small but Mighty H. Schwarz, R. Kretschmer, M. Schlangen Chemistry - An Asian Journal 2012, 7, 1214–1220, 10.1002/asia.201101045
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813 Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry H. Schwarz, N. Dietl, M. Schlangen Angewandte Chemie International Edition 2012, 51, 5544–5555, 10.1002/anie.201108363
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812 Neutral Metal Atoms Acting as a Leaving Group in Gas-Phase SN2 Reactions: M(CH3)+ + NH3 -> CH3NH3+ + M (M = Zn, C, Hg) H. Schwarz, R. Kretschmer, M. Schlangen, M. Kaupp Organometallics 2012, 31, 3816–3824, 10.1021/om300116c
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806 Direct Conversion of Methane into Formaldehyde Mediated by [Al2O3]•+ at Room Temperature H. Schwarz, Z. C. Wang, N. Dietl, R. Kretschmer, J. B. Ma, T. Weiske, M. Schlangen Angewandte Chemie International Edition 2012, 51, 3703–3707, 10.1002/anie.201200015
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804 C-N and C-C Bond Formations in the Thermal Reactions of "Bare" Ni(NH2)+ with C2H4: Mechanistic Insight on the Metal-Mediated Hydroamination of an Unactivated Olefin H. Schwarz, R. Kretschmer, M. Schlangen Angewandte Chemie International Edition 2012, 51, 3483–3488, 10.1002/anie.201104433
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781 "Rollover" cyclometalation - early history, recent developments, mechanistic insights and application aspects H. Schwarz, B. Butschke Chemical Science 2012, 3, 308–326, 10.1039/c1sc00651g
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777 Mechanistic Aspects and Elementary Steps of N-H Bond Activation of Ammonia and C-N Coupling Induced by Gas-Phase Ions: A Combined Experimental/Computational Exercise H. Schwarz, R. Kretschmer, M. Schlangen Chemistry - A European Journal 2012, 18, 40–49, 10.1002/chem.201102494
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771 Catalytic Redox Reactions in the CO/N2O System Mediated by the Bimetallic Oxide-Cluster Couple AlVO3+/AlVO4+ H. Schwarz, Z. C. Wang, N. Dietl, R. Kretschmer, T. Weiske, M. Schlangen Angewandte Chemie International Edition 2011, 50, 12351–12354, 10.1002/anie.201105691
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668 Probing elementary steps of nickel-mediated bond activation in gas-phase reactions: Ligand- and cluster-size effects H. Schwarz, M. Schlangen Journal of Catalysis 2011, 284, 126–137, 10.1016/j.cat.2011.03.020
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663 Structure of the Oxygen-Rich Cluster Cation Al2O7+ and its Reactivity toward Methane and Water H. Schwarz, Z. C. Wang, T. Weiske, R. Kretschmer, M. Schlangen, M. Kaupp Journal of the American Chemical Society 2011, 133, 16930–16937, 10.1021/ja206258x
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662 The Missing Link: The Gas-Phase Generation of Platinum-Methylidyne Clusters PtnCH+ (n = 1, 2) and Their Reactions with Hydrocarbons and Ammonia H. Schwarz, B. Butschke Chemistry - A European Journal 2011, 17, 11761–11772, 10.1002/chem.201101018
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661 Chemie mit Methan: Studieren geht über Probieren! H. Schwarz Angewandte Chemie 2011, 123, 10276–10297, 10.1002/ange.201006424
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660 Chemistry with Methane: Concepts Rather than Recipes H. Schwarz Angewandte Chemie International Edition 2011, 50, 10096–10115, 10.1002/anie.201006424
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659 On the Activation of Chloromethanes by Cyclometalated [Pt(bipy – H)]+ in the Gas Phase: A Mechanistic Study H. Schwarz, B. Butschke International Journal of Mass Spectrometry 2011, 306, 108–113, 10.1016/j.ijms.2010.08.030
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656 Thermal Activation of Methane and Ethene by Bare MO.+ (M = Ge, Sn, and Pb): A Combined Theoreti-cal/Experimental Study K. Chen, Z. C. Wang, M. Schlangen, Y. D. Wu, X. Zhang, H. Schwarz Chemistry - A European Journal 2011, 17, 9619–9625, 10.1002/chem.201101538
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602 Effiziente und selektive Monomethylierung kontra N-H-Bindungsaktivierung von Ammoniak: atomares Zink als Abgangsgruppe in einer SN2-Reaktion von nacktem Zn(CH3)+ und NH3 H. Schwarz, R. Kretschmer, M. Schlangen Angewandte Chemie 2011, 123, 5499–5503, 10.1002/ange.201100096
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601 Efficient and Selective Gas-Phase Monomethylation versus N-H Bond Activation of Ammonia by Bare Zn(CH3)+: Atomic Zinc as a Leaving Group in an SN2 Reaction H. Schwarz, R. Kretschmer, M. Schlangen Angewandte Chemie International Edition 2011, 50, 5387–5391, 10.1002/anie.201100096
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590 Bonding in cationic MOHn+ (M = K - La, Hf - Rn; n = 0 - 2): DFT performances and periodic trends H. Schwarz, X. Zhang Theoretical Chemistry Accounts 2011, 129, 389–399, 10.1007/s00214-010-0861-0
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589 Über dir Rolle von [CuO]+ bei spinselektiven Wasserstoff- und Sauerstoff-Übertragungen in der Aktivierung von Methan H. Schwarz, N. Dietl, C. van der Linde, M. Schlangen, M. K. Beyer Angewandte Chemie 2011, 123, 5068–5072, 10.1002/ange.201100606
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588 Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane H. Schwarz, N. Dietl, C. van der Linde, M. Schlangen, M. K. Beyer Angewandte Chemie International Edition 2011, 50, 4966–4969, 10.1002/anie.201100606
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521 Room-Temperature C-H Bond Activation of Methane by Bare [P4O10].+ H. Schwarz, N. Dietl, M. Engeser Angewandte Chemie International Edition 2009, 48, 4861–4863, 10.1002/anie.200901596
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490 Neutralization-reionization study of the allyloxide anion H. Schwarz, D. Schröder, J. Roithová International Journal of Mass Spectrometry 2011, 301, 84–89, 10.1016/j.ijms.2010.07.007
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489 Thermal Activation of N-H Bonds by Transition-Metal Oxide Cations: Does a Hierarchy Exist in First Row? H. Schwarz, R. Kretschmer, X. Zhang, M. Schlangen Chemistry - A European Journal 2011, 17, 3886–3892, 10.1002/chem.201003620
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488 Thermal C-H Bond Activation of Benzene, Toluene, and Methane with Cationic [J(X)(bipy)]+ (M = Ni, Pd, Pt; X = CH3, Cl; bipy = 2,2\'-bipyridine): A Mechanistic Study H. Schwarz, B. Butschke Organometallics 2011, 30, 1599–1598, 10.1021/om101138d
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420 Generation, Reactivity Towards Hydrocarbons, and Electronic Structure of Heteronuclear Vanadium Phosphorous Oxygen Cluster Ions H. Schwarz, N. Dietl, R. F. Höckendorf, M. Schlangen, M. Lerch, M. K. Beyer Angewandte Chemie International Edition 2011, 50, 1430–1434, 10.1002/anie.201005258
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419 Directed, Remote Gas-Phase C2H and C2C Bond Activations by Metal Oxide Cations Anchored to a Nitrile Group H. Schwarz, N. Dietl, M. Schlangen Chemistry - A European Journal 2011, 17, 1783–1788, 10.1002/chem.201003041
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407 Isomerization of an N-Heterocyclic Germylene to an Azagermabenzen-1-ylidene and Its Coupling to a Unique Bis(germylene) S. Yao, X. Zhang, Y. Xiong, H. Schwarz, M. Driess Organometallics 2010, 29, 5353–5357, 10.1021/om100383y
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406 Aktivierung der C-H-Bindung von Methan bei Raumtemperatur durch nacktes [P4O10]+ N. Dietl, M. Engeser, H. Schwarz Angewandte Chemie 2009, 121, 4955–4957, 10.1002/ange.200901596
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404 Darstellung, Reaktivität gegenüber Kohlenwasserstoffen und elektronische Struktur von heteronuclearen Vanadium-Phosphor-Sauerstoff-Clusterionen H. Schwarz, N. Dietl, R. F. Höckendorf, M. Schlangen, M. Lerch, M. K. Beyer Angewandte Chemie 2011, 123, 1466–1470, 10.1002/ange.201005258
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402 Mechanistic Study on the Gas-Phase Generation of "Rollover"-Cyclometalated [M(bipy - H)]+ (M = Ni, Pd, Pt) B. Butschke, H. Schwarz Organometallics 2010, 29, 6002–6011, 10.1021/om100757e
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401 Thermal Activation of Methane by Diatomic Metal Oxide Radical Cations: PbO+. as One of the Missing Pieces H. Schwarz, X. Zhang ChemCatChem 2010, 2, 1391–1394, 10.1002/cctc.201000259
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400 N2 Activation by a Hafnium Complex: A DFT Study on CO-Assisted Dinitrogen Cleavage and Functionalization B. Butschke, X. Zhang, H. Schwarz Chemistry - A European Journal 2010, 16, 12564–12569, 10.1002/chem.201001635
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399 Conversion of Methane to Methanol: Nickel, Palladium, and Platinum (d9) Cations as Catalysts for the Oxidation of Methane by Ozone at Room Temperature A. Bozovic, D. K. Bohme, M. Schlangen, S. Feil, X. Zhang, A. A. Viggiano, G. K. Koyanagi, H. Schwarz Chemistry - A European Journal 2010, 16, 11605–11610, 10.1002/chem.201000627
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397 Selective C2H versus O2H Bond Activation of CH3OH upon Elextrospraying Methanolic Solutions of MX2 (M = Fe, Co, Ni; X = Br, I): A DFT-Study M. Schlangen, H. Schwarz ChemCatChem 2010, 2, 799–802, 10.1002/cctc.201000042
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393 Bonding in Cationic MCH2+ (M = K-La, Hf-Rn): A Theoretical Study on Periodic Trends H. Schwarz, X. Zhang Chemistry - A European Journal 2010, 16, 5882–5888, 10.1002/chem.201000567
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392 Competitive Hydrogen-Atom Abstraction versus Oxygen-Atom and Electron Transfers in Gas-Phase Reactions of [X4O10]C+ (X=P, V) with C2H4 H. Schwarz, N. Dietl, M. Engeser Chemistry - A European Journal 2010, 16, 4452–4456, 10.1002/chem.201000310
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391 Ion-Molecule Reactions of "Rollover" Cyclometalated [Pt(bipy-H)]+ (bipy = 2,2'-bipyridine) with Dimethyl Ether in Comparison with Dimethyl Sulfide: An Experimental/Computational Study H. Schwarz, B. Butschke, S. Ghassemi Tabrizi Chemistry - A European Journal 2010, 16, 3962–3969, 10.1002/chem.200902742
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386 Reactivity Pattern in the Room-Temperature Activation of NH3 by the Main-Group Atomic Ions Ga+, Ge+, As+ and Se+ H. Schwarz, V. Kapishon, D. K. Bohme, X. Zhang, G. K. Koyanagi European Journal of Inorganic Chemistry 2010, 2010, 1516–1521, 10.1002/ejic.200901126
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379 On the Gas-Phase Decomposition of Acyclic Ethers Mediated by "Rollover" Cyclometalated [Pt(bipy - H)]+ (bipy = 2,2'-bipyridine): A Mechanistic Study H. Schwarz, B. Butschke, S. Ghassemi Tabrizi International Journal of Mass Spectrometry 2010, 291, 125–132, 10.1016/j.ijms.2010.01.015
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298 Metal-dependent alternative activation of O-H and C-H bonds of methanol: on the formation and structure of "bare" [M,C,H3,O]+ complexes (M = Fe, Co, Ni) in the gas phase H. Schwarz, M. Schlangen Chemical Communications 2010, 46, 1878–1880, 10.1039/b924493j
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268 Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution M. Driess, S. Yao, Y. Xiong, X. Zhang, M. Schlangen, H. Schwarz, C. Milsmann Angewandte Chemie International Edition 2009, 48, 4551–4455, 10.1002/anie.200901132
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237 Generation of Gas-Phase Nanosized Vanadium Oxide Clusters from a Mononuclear Precursor by Solution Nucleation and Electrospray Ionization H. Schwarz, X. Zhang Chemistry - A European Journal 2010, 16, 1163–1167, 10.1002/chem.200902810
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231 Ligand and electronic-structure effects in metal-mediated gas-phase activation of methane: A cold approach to a hot problem H. Schwarz, M. Schlangen Dalton Transactions 2009, 46, 10155–10165, 10.1039/b915165f
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230 Isotope-Sensitive Degenerate [1,3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization H. Schwarz, X. Zhang, W. Zummack, D. Schröder, F. A. Weinhold Chemistry - A European Journal 2009, 15, 11815–11819, 10.1002/chem.200902176
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229 A DFT-Based Analysis of the Grossly Varying Reactivity Pattern in Room-Temperature Activation and Dehydrogenation of CH4 by Main-Group Atomic M+ (M = Ga, Ge, As, and Se) H. Schwarz, X. Zhang Chemistry - A European Journal 2009, 15, 11559–11565, 10.1002/chem.200901956
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227 Thermal Homo- and Heterolytic C-H Bond Activation of Ethane and Propane by Bare [P4O10]*+: Regioselectivities, Kinetic Isotope Effects, and Density Functional Theory Based Potential-Energy Surfaces H. Schwarz, N. Dietl, M. Engeser Chemistry - A European Journal 2009, 15, 11100–11104, 10.1002/chem.200901568
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221 A Redox Non-Innocent Ligand Controls the Life Time of a Reactive Quartet Excited State - An MCSCF Study of [Ni(H)(OH)]+ H. Schwarz, Y. Dede, X. Zhang, M. Schlangen, M. H. Baik Journal of the American Chemical Society 2009, 131, 12634–12642, 10.1021/ja90293f
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220 Thermal N-H Bond Activation on Anionic and Cationic Platinum clusters: Non-Predetermined Reaction Pathways Indicate Transitions to a Bulk Surface Reactivity H. Schwarz, M. Ončák, Y. Cao, R. Höckendorf, M. K. Beyer, R. Zahradník Chemistry - A European Journal 2009, 15, 8465–8474, 10.1002/chem.200900677
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219 Thermal C-H Bond Activation of Benzene with Cationic [Pt(CX3)(L)] Complexes in the Gas Phase: A Combined Experimental/Theoretical Study (X=H, D; L=1,10-Phenanthroline, 2,2'-Bipyrimidine, 2,2'-Bipyridine, and (o,o'-Cl2C6H3)N=C(CH3)-C(CH3)=N(o,o'-Cl2C6H3)) H. Schwarz, D. Schröder, B. Butschke Organometallics 2009, 28, 4340–4349, 10.1021/om900388k
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118 Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers H. Schwarz, B. Butschke, M. Schlangen, D. Schröder International Journal of Mass Spectrometry 2009, 283, 3–8, 10.1016/j.ijms.2008.10.019
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95 Room-Temperature Alkyne-Nitrile Metathesis and Unambiguous Proof for the Existence of a High-Valent Iron-Nitrido Dication in the Gas Phase H. Schwarz, J. P. Boyd, M. Schlangen, A. Grohmann Helvetica Chimica Acta 2008, 91, 1430–1434, 10.1002/hlca.200890155
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94 Competitive Intramolecular Aryl- and Alkyl-C-H Bond Activation and Ligand Evaporation from Gaseous Bisimino Complexes [Pt(L)(CH3)((CH3)2S)]+ (L = C6H5N=C(CH3)-C(CH3)=NC6H5) H. Schwarz, B. Butschke, M. Schlangen, D. Schröder Helvetica Chimica Acta 2008, 91, 1902–1915, 10.1002/hlca.200890204
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93 "Roll-over" Cyclometalation of 2,2'-Bipyridine Platinum(II) Complexes in the Gas Phase: A Combined Experimental and Computational Study H. Schwarz, B. Butschke, M. Schlangen, D. Schröder Chemistry - A European Journal 2008, 14, 11050–11060, 10.1002/chem.200801658
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92 DFT Studies on the Thermal Activation of Molecular Oxygen by Bare [Ni(H)(OH)]+ H. Schwarz, X. Zhang, M. Schlangen, M. H. Baik, Y. Dede Helvetica Chimica Acta 2009, 92, 151– 10.1002/hlca.200800411
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91 Ligand Effects on the Mechanisms of Thermal Bond Activation in the Gas-Phase Reactions NiX+/CH4 → Ni(CH3)+/HX (C = H, CH3, OH, F) H. Schwarz, M. Schlangen Helvetica Chimica Acta 2008, 91, 2203–2210, 10.1002/hlca.200890238
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90 Gas-phase activation of methane by ligated transition-metal cations H. Schwarz, D. Schröder Proceedings of the National Academy of Sciences of the United States of America 2008, 105, 18114–18119, 10.1073/pnas.0801849105
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89 On the Mechanisms of Degenerate Ligand Exchange in [M(CH3)]+/CH4 Couples (M = Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt) as Explored by Mass Spectrometric and Computational Studies: Oxidative Addition/Reductive Elimination versus Sigma-Complex-Assisted Metathesis H. Schwarz, M. Armélin, M. Schlangen Chemistry - A European Journal 2008, 14, 5229–5236, 10.1002/chem.200800029
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88 Methanaktivierung durch (Al2O3)x+ (x = 3, 4, 5): die Rolle von Sauerstoff-zentrierten Radikalen bei thermischer Abstraktion eines Wasserstoffatoms von Methan M. K. Beyer, J. Döbler, S. Feyel, H. Schwarz, J. Sauer, R. Höckendorf Angewandte Chemie 2008, 120, 1972–1976, 10.1002/ange.200704791
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87 Activation of Methane by Oligomeric (Al2O3)x+ (x = 3, 4, 5): The Role of Oxygen-Centered Radicals in Thermal Hydrogen-Atom Abstraction M. K. Beyer, H. Schwarz, R. Höckendorf, J. Döbler, S. Feyel, J. Sauer Angewandte Chemie International Edition 2008, 47, 1946–1950, 10.1002/anie.200704791
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86 Insertion of Molecular Oxygen in Transition-Metal Hydride Bonds, Oxygen-bond Activation, and Unimolecular Dissociation of Metal Hydroperoxide Intermediates H. Schwarz, M. Schlangen Helvetica Chimica Acta 2008, 91, 379–386, 10.1002/hlca.200890043
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